MCQ
The coordination number and the oxidation state of the element $‘E’$ in the complex $[E(en)_2(C_2O_4)]NO_2$ (where (en) is ethylene diamine) are, respectively
  • A
    $6$ and $2$
  • B
    $4$ and $2$
  • C
    $4$ and $3$
  • D
    $6$ and $3$

Answer

In the given complex we have two bidentate ligands

(i.e $en$ and $C_2O_4$ ), so coordination number of $E$ is $6$

                        $(2 \times 2 + 1 \times 2 = 6)$

Let the oxidation state of $E$ in complex be $x$, then

$[x + (-2) = 1]$ or $x -2 = 1$

or $x = + 3$, so its oxidation state is $+ 3$ Thus option $(d)$ is correct.

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