- A$\mathrm{PF}_3<\mathrm{BF}_3<\mathrm{C} \ell \mathrm{F}_3$
- B$\mathrm{BF}_3<\mathrm{PF}_3<\mathrm{C} / \mathrm{F}_3$
- ✓$\mathrm{C} / \mathrm{F}_3<\mathrm{PF}_3<\mathrm{BF}_3$
- D$\mathrm{BF}_3=\mathrm{PF}_3<\mathrm{C} \ell \mathrm{F}_3$
Order of bond angle is
$\mathrm{ClF}_3<\mathrm{PF}_3<\mathrm{BF}_3$
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$($ given $=$ Atomic number of $\mathrm{Ni}: 28)$
${\text{2PQ}} \rightleftharpoons {{\text{P}}_2}{\text{ + }}{{\text{Q}}_2}\,;\,\,\,\,{{\text{K}}_1}{\text{ = 2}}{\text{.5 }} \times \,{\text{1}}{{\text{0}}^5}\,$
${\text{PQ + }}\frac{1}{2}{R_2} \rightleftharpoons PQR\,;\,\,\,\,{{\text{K}}_2}{\text{ = 5 }} \times \,{\text{1}}{{\text{0}}^{ - 3}}\,$
The value of equilibrium constant for reaction
$\frac{1}{2}{{\text{P}}_2}{\text{ + }}\frac{1}{2}{{\text{Q}}_2}{\text{ + }}\frac{1}{2}{R_2} \rightleftharpoons PQR\,$ is
|
List $I$ (Molecule Species) |
List $I$ ( Property Shape ) |
| $A$ $\mathrm{SO}_2 \mathrm{Cl}_2$ | $I$ Paramagnetic |
| $B$ $NO$ | $II$ Diamagnetic |
| $C$ $\mathrm{NO}_2^{-}$ | $III$ Tetrahedral |
| $D$ $\mathrm{I}_3^{-}$ | $IV$ Linear |
Choose the correct answer from the options given below :

$(A)$ $\mathrm{Ni}(\mathrm{CO})_{4}$
$(B)$ $\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}$
$(C)$ $\mathrm{Na}_{2}\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]$
$(D)$ $\mathrm{PdCl}_{2}\left(\mathrm{PPh}_{3}\right)_{2}$