- A$PF_3 < PCl_3 < PBr_3 > PI_3$
- ✓$PF_3 < PCl_3 < PBr_3 < PI_3$
- C$PF_3 > PCl_3 > PBr_3 > PI_3$
- D$PF_3 > PCl_3 < PBr_3 > PI_3$
If $\mathrm{C.A}$. $=$ same Hybridisation same
$L.P.$ $=$ same Bond angle $\propto$ size of side atom
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$(1)$ $C{H_3}C{H_2}C{H_2}Cl + $ $\begin{array}{*{20}{c}}
{\,\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,C{H_3}} \\
{\,\,\,|}
\end{array}} \\
{C{H_3} - C - {O^ - }} \\
{\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$ $(2)$ $C{H_3}C{H_2}C{H_2}I + $$\begin{array}{*{20}{c}}
{\,\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,C{H_3}} \\
{\,\,\,|}
\end{array}} \\
{C{H_3} - C - {O^ - }} \\
{\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$
$(3)$ $\begin{array}{*{20}{c}}
{{H_3}C - CH - C{H_3}} \\
{|\,\,\,\,} \\
{Br\,\,\,}
\end{array}$ $+CH_3O^-$ $(4)$ $\begin{array}{*{20}{c}}
{{H_3}C - CH - C{H_3}} \\
{|\,\,\,\,} \\
{Br\,\,\,}
\end{array}$ $+CH_3S^-$
The temperature at which the rate constant of the reaction is $10^{-4} s ^{-1}$ is .............. $K$.
(Rounded-off to the nearest integer)
[Given: The rate constant of the reaction is $10^{-5} s ^{-1}$ at $500 K$.]
$A$ and $B$ are :