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8.1. Aldehydes and ketones — Chemistry STD 12 Science — Question

CBSE BoardEnglish MediumSTD 12 ScienceChemistry8.1. Aldehydes and ketones1 Mark
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Answer

Correct option: D.
Gattermann reaction
d
The given reaction is known as Gattermann reaction.In this reaction, aromatic compound such as benzene or phenol is treated with a mixture of $HCN$ and dry $HCl$ gas under pressure and in the presence of anhydrous aluminum chloride or zinc chloride to introduce a formyl group in the aromatic nucleus.

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$\begin{matrix}
   O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   H-O-C-{{(C{{H}_{2}})}_{n}}-C-O-H\xrightarrow[\Delta ]{}product  \\
\end{matrix}$ ,

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$\begin{array}{*{20}{c}}
  {C{H_3} - CH - C{H_2} - C{H_2} - CH - C{H_3}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,} \\ 
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$[X]$ will be :

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