- ADehydrogenation reaction
- BHydrogenation reaction
- CDehydration reaction
- ✓Heterolytic fission reaction
$(a)$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,\begin{array}{*{20}{c}}
{\,I} \\
|
\end{array}} \\
{C{H_3} - C - H} \\
{\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$ , Isopropyl iodide $(2^o)$
$(b)$ $\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,\,\,H\,\,\,\,\,\,H\,\,\,\,\,H} \\
{\,\,\,|\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|}
\end{array}} \\
{H - C - C - C - I} \\
{\,\,\,\,|\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,|\,} \\
{\,\,\,\,\,\,\,\,\,\,H\,\,\,\,\,\,H\,\,\,\,\,C{H_3}}
\end{array}$, sec- Butyl iodide $(2^o)$
$(c)$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\begin{array}{*{20}{c}}
{\,\,\,\,\,\,C{H_3}} \\
|
\end{array}\,} \\
{{H_3}C - C - I} \\
{\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$ , tert - Butyl iodide $(3^o)$
$(d)$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{array}{*{20}{c}}
{\,\,\,C{H_3}\,\,H\,\,} \\
{|\,\,\,\,\,\,\,\,\,|}
\end{array}} \\
{C{H_3} - C{H_2} - C - C - Cl} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|\,} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CH{\,_3}\,H\,\,\,\,\,\,}
\end{array}$, Neohexyl chloride $(1^o)$
Thus, $(d)$ is a primary $(1^o)$ halide.
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Choose the correct answer from the options given below:
$Cl_2(aq) + H_2S(aq) \to S(s) + 2H^+(aq) + 2Cl^-(aq)$
The rate equation for this reaction is rate $= k[Cl_2][H_2S]$ Which of these mechanisms is/are consistent with this rate equation ?
$A.\,C{l_2} + {H_2}S \to {H^ + } + C{l^ - } + C{l^ + } + H{S^- }$ (slow)
$C{l^ + } + H{S^ - } \to {H^ + } + C{l^ - } + {S}$ (fast)
$B.\, H_2S \Leftrightarrow H^+ + HS^-$ (fast equilibrium)
$Cl_2 + HS^-\to 2Cl^-+ H^+ + S$ (slow)