- Alone pair of phosphorus is optically inert
- Blone pair of phosphorus resides in almost pure $p-$ orbital
- Clone pair of phosphorus resides at $sp^3$ orbital
- ✓lone pair of phosphorus resides in almost pure $s-$ orbital
According to Drago's rule lone pair on phosphorus resides in almost pure s-orbital, hence due to non-directionalnature, its overlapping tendency is greatly reduced in comparison to a lone pair present in hybrid orbital, which is directional as present in $\overset{\,\,\centerdot \,\,\centerdot \,\,\,\,\,\,\,\,}{\mathop{\text{N}{{\text{H}}_{3}}}}\,$.
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$MnCl _2+ K _2 S _2 O _8+ H _2 O \longrightarrow KMnO _4+ H _2 SO _4+ HCl$ (equation not balanced).
Few drops of concentrated $HCl$ were added to this solution and gently warmed. Further, oxalic acid ( $225 mg$ ) was added in portions till the colour of the permanganate ion disappeared. The quantity of $MnCl _2$ (in $mg$ ) present in the initial solution is. . . . . . . . . (Atomic weights in $g mol ^{-1}: Mn =55, Cl =35.5$ )
($A$) $\mathrm{C}_2^{2-}$ is expected to be diamagnetic
($B$) $\mathrm{O}_2{ }^{2+}$ is expected to have a longer bond length than $\mathrm{O}_2$
($C$) $\mathrm{N}_2^{+}$and $\mathrm{N}_2^{-}$have the same bond order
($D$) $\mathrm{He}_2^{+}$has the same energy as two isolated He atoms


