MCQ
The pair not correctly matched is
  • A
    $[CoBr(NH_3)_5]SO_4$ and $[CoSO_4(NH_3)_5]Br$ $ \Rightarrow $ ionisation isomerism
  • $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 .H_2O$ $ \Rightarrow $ Linkage isomerism
  • C
    $[Cr(H_2O)_4(NO_2)_2]Cl$ and $[Cr(H_2O)_4(ONO)_2]Cl$ $ \Rightarrow $ Linkage Isomerism
  • D
    $[Cr(H_2O)_5Cl]Cl_2$ and $[Cr(H_2O)_4Cl_2] Cl. H_2O$ $ \Rightarrow $ Hydrate isomerism

Answer

Correct option: B.
$[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 .H_2O$ $ \Rightarrow $ Linkage isomerism
b

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   \begin{matrix}
   \,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\,  \\
   \,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
   C{{H}_{3}}-C-C{{H}_{2}}-C{{H}_{2}}-C{{H}_{2}}-C{{H}_{2}}-C-H  \\
\end{matrix}  \\
   \downarrow KOH  \\
\end{matrix}$

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