MCQ
The reaction is spontaneous if the cell potential is
- APositive
- BNegative
- CZero
- DInfinite
Where $s.r.p$ . = Standard reduction potential
If $EMF$ is positive then the reaction is spontaneous
For e.g. in Galvanic cell
$(a)$ $EMF = 1.1\,volt$
$(b)$ Cathode is made of copper
$(c)$ Anode is made of Zinc
$EMF$ $= 0.34 \,-(-0.76) = 1.1\,volt$ .
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$2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{O}_{2}+4 \mathrm{H}^{\oplus}+4 \mathrm{e}^{-} ; \mathrm{E}_{\mathrm{red}}^{0}=1.23 \mathrm{V}$
$(\mathrm{R}=8.314 \;\mathrm{J} \mathrm{mol}^{-1} \mathrm{K}^{-1} ; \text { Temperature }=298 \;\mathrm{K} ;$ oxygen under std. atm. pressure of $1 \;bar$)
