- ACurrent drawn from the cell
- BTemperature of electrolyte
- CConcentration of electrolyte
- ✓The $e.m.f.$ of the cell
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${{C}_{3}}{{H}_{7}}OH\underset{160-{{180}\,^{o}}C}{\mathop{\xrightarrow{Conc.{{H}_{2}}S{{O}_{4}}}}}\,X\underset{{}}{\mathop{\xrightarrow{B{{r}_{2}}}}}\,Y\underset{Alc.KOH}{\mathop{\xrightarrow{\text{Excess of}}}}\,Z$
The time taken for $A$ to become $1 / 4^{\text {th }}$ of its inital concentration is twice the time taken to become $1 / 2$ of the same. Also, when the change of concentration of $B$ is plotted against time, the resulting graph gives a straight line with a negative slope and a positive intercept on the concentration axis. The overall order of the reaction is . . . . .
structure of $(A)$ is
$(I)\,[Ni(CO)_4]$ $(II)\, [Mn(CN)_6]^{4-}$ $(III)\, [Cr(NH_3)_6]^{3+}$ $(IV) \,[CoF_6]^{3 -}$