MCQ
The trivalent ion having largest size in following is
- A$Ti$
- B$Zr$
- C$Hf$
- ✓$La$
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|
List$-I$ (Chemical Reaction) |
List$-II$ (Reagent used) |
| $(a)$ $\mathrm{CH}_{3} \mathrm{COOCH}_{2} \mathrm{CH}_{3} \rightarrow \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}$ |
$(i)$ $\mathrm{CH}_{3} \mathrm{MgBr} / \mathrm{H}_{3} \mathrm{O}^{+}$ $(1 .$ equivalent $)$ |
| $(b)$ $\mathrm{CH}_{3} \mathrm{COOCH}_{3} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}$ | $(ii)$ $\mathrm{H}_{2} \mathrm{SO}_{4} / \mathrm{H}_{2} \mathrm{O}$ |
| $(c)$ $\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{N} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}$ | $(iii)$ $\mathrm{DIBAL}-\mathrm{H} / \mathrm{H}_{2} \mathrm{O}$ |
| $(d)$ $\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{N} \rightarrow \mathrm{CH}_{3}CO\mathrm{CH}_{3}$ | $(iv)$ $\mathrm{SnCl}_{2}, \mathrm{HCl} / \mathrm{H}_{2} \mathrm{O}$ |
Choose the most appropriate match :
$[Image]$
$(A)$ $o-$Nitroaniline and $p-$nitroaniline are the predominant products
$(B)$ $p-$Nitroaniline and $m-$nitroaniline are the predominant products
$(C)$ $HNO _{3}$ acts as an acid
$(D)$ $H _{2} SO _{4}$ acts as an acid
(The atomic mass of $Na$ is $23\, g / mol$ ) :
| Column $I$ | Column $II$ |
| $(a)$ Urea | $(i) i < 1$ |
| $(b) FeCl_3$ | $(ii) i = 1$ |
| $(c)$ Benzoic acid in Benzene | $(iii) i = 2$ |
| $(d) MgSO_4$ | $(iv) i = 4$ |