MCQ
Thiophene and benzene are separated by
- ASulphonation of thiophene
- ✓Sulphonation of benzene
- CNitration of thiophene
- DNitration of benzene
Shaking a mixture of benzene and thiophene with sulfuric acid at room temperature causes sulfonation of the thiophene but leaves the benzene untouched.
The thiophene sulfonic acid dissolves in the sulfuric acid layer, which you can separate.
You can then wash, dry, and distill the benzene in the usual way.
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| List-I (Complex)} | List-II (Hybridisation of central metal ion) |
| (A) $\left[\mathrm{CoF}_{6}\right]^{3-}$ | (I) $ d^2 sp ^3$ |
| (B) $\left[\mathrm{NiCl}_{4}\right]^{2}$ | (II) $sp ^3$ |
| (C) $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}$ | (III) $ sp ^3 d^2$ |
| (D) $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ | (IV) $dsp ^2$ |
$CaCO _3( s ) \rightleftharpoons CaO ( s )+ CO _2( g )$
For this equilibrium, the correct statement(s) is (are)
$(A)$ $\Delta H$ is dependent on $T$
$(B)$ $K$ is independent of the initial amount of $CaCO _3$
$(C)$ $K$ is dependent on the pressure of $CO _2$ at a given $T$
$(D)$ $\Delta H$ is independent of the catalyst, if any
