Question
Two samples of gas initially at the same temperature and pressure are compressed from volume V to $\frac{\text{V}}{2}.$ One sample is compressed isothermally and the other adiabatically. In which case will the pressure be higher? Explain.

Answer

Let Pa and Pi be the final pressure during adiabatic and isothermal compression respectively. In case isothermal compression.
$\text{PV}=\text{P}_\text{i}\Big(\frac{\text{V}}{2}\Big)$ or $\text{P}_\text{i}=2\text{P}\dots\text{(i)}$
In case of adiabatic compression,
$\text{PV}^\gamma=\text{P}_\text{i}\Big(\frac{\text{V}}{2}\Big)^\gamma$ or $\text{P}_\text{a}=2^\gamma\text{P}\dots\text{(ii)}$
$\therefore\frac{\text{P}_\text{a}}{\text{P}_\text{i}}=\frac{2^\gamma}{2}>1,$ because $\gamma>1$
$\therefore\text{P}_\text{a}>\text{P}_\text{i}$
Hence, final pressure during adiabatic compression is greater than the pressure during isothermal compression.

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