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What are Carbohydrates? How are they classified?

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How would you account for the following:
  1. Among lanthanoids, Ln (III) compounds are predominant. However, occasionally in solutions or in solid compounds, +2 and +4 ions are also obtained.
  2. The EoM2+/M for copper is positive (0.34V). Copper is the only metal in the first series of transition elements showing this behaviour.
  3. The metallic radii of the third (5d) series of transition metals are nearly the same as those of the corresponding members of the second series.
Why are different colours observed in octahedral and tetrahedral complexes for the same metal and same ligands?
Neeta was experimenting in the lab to study the chemical reactivity of alcohols. She carried out a dehydration reaction of propanol at 140°C to 180°C. Different products were obtained at these two temperatures.
a. Identify the major product formed at 140°C and the substitution mechanism followed in this case.
b. Identify the major product formed at 180°C and the substitution mechanism followed in this case.
Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place. Further show:
  1. Which of the electrode is negatively charged?
  2. The carriers of the current in the cell.
  3. Individual reaction at each electrode.
Complete the following chemical equations:
  1. $\text{MnO}_{4}^{-}+\text{C}_{2}\text{O}_{4}^{2-}+\text{H}+\rightarrow$
  2. $\text{KMnO}_{4}\xrightarrow{\text{heated}}$
  3. $\text{Cr}_{2}\text{O}_{4}^{2-}+\text{H}_{2}\text{S}+\text{H}^{+}+\rightarrow$
Write the mechanism of the reaction of HI with methoxymethane.
Calculate the standard cell potentials of galvanic cell in which the following reactions take place:
Fe2+(aq) + Ag+ (aq) → Fe3+(aq) + Ag(s)
Calculate the $\triangle_\text{r}\text{G}^\ominus$ and equilibrium constant of the reactions.
Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is 1.504 g mL-1?
Write only equations to obtain 1º, 2º and 3° alcohols from aldehydes and ketones.
Draw figure to show the splitting of d orbitals in an octahedral crystal field.