Question
What is the action of phosphorus pentachloride on
(1) Diethyl ether
(2) Ethyl methyl ether
(3) Methyl phenyl ether (anisole)?

Answer

(1) Diethyl ether : When diethyl ether is heated with ethyl methyl ether, ethyl chloride is formed.
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(2) Ethyl methyl ether : When ethyl methyl ether is heated with phosphorus pentachloride, a mixture of ethyl chloride and methyl chloride is formed.
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(3) Methyl phenyl ether (Anisole) : When methyl phenyl ether is heated with phosphorus pentachloride, a mixture of methyl chloride, chlorobenzene is formed.
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