MCQ
Which among the given haloalkanes develop colour when exposed to light?
- A$\text{R−Br}$ and $\text{R−Cl}$
- B$R−I$ and $R−F$
- C$\text{R−Cl}$ and $\text{R−Br}$
- ✓$\text{R−Br}$ and $R−I$
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$2 A + B \longrightarrow C + D$
| Experiment | $[ A ] / molL ^{-1}$ | $[ B ] / molL ^{-1}$ | Initial $rate/molL$ $^{-1}$ $\min ^{-1}$ |
| $I$ | $0.1$ | $0.1$ | $6.00 \times 10^{-3}$ |
| $II$ | $0.1$ | $0.2$ | $2.40 \times 10^{-2}$ |
| $III$ | $0.2$ | $0.1$ | $1.20 \times 10^{-2}$ |
| $IV$ | $X$ | $0.2$ | $7.20 \times 10^{-2}$ |
| $V$ | $0.3$ | $Y$ | $2.88 \times 10^{-1}$ |
$X$ and $Y$ in the given table are respectively :
In the above first order reaction the concentration of $\mathrm{PCl}_{5}$ reduces from initial concentration $50\, mol\,\mathrm{L}^{-1}$ to $10\, \mathrm{~mol} \,\mathrm{~L}^{-1}$ in $120\, minutes$ at $300\, \mathrm{~K}$. The rate constant for the reaction at $300\, \mathrm{~K}$ is $\mathrm{X}$ $\times 10^{-2} \mathrm{~min}^{-1}$. The value of $x$ is $......$
$[$ Given $\log 5=0.6989]$