a (a) Sucrose does not show mutarotation due to non reducing nature.
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Assertion : Alpha $\left( \alpha \right) - $ amino acids exist as internal salt in solution as they have amino and carboxylic acid groups in near vicinity.
Reason : $H^+$ ion given by carboxylic group $(-COOH)$ is captured by amino group $(-NH_2)$ having lone pair of electrons.