- ✓$Ne$
- B$F$
- C$\mathrm{O}_2$
- D$\mathrm{\sim N}_2$
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$\mathrm{A}+\mathrm{B} \rightarrow \mathrm{C}$
$\text { rate }=\mathrm{k}[\mathrm{A}]^{1 / 2}[\mathrm{~B}]^{1 / 2}$
The reaction is initiated by taking $1 \mathrm{M}$ concentration $A$ and $B$ each. If the rate constant $(k)$ is $4.6 \times 10^{-2} \mathrm{~s}^{-1}$, then the time taken for $\mathrm{A}$ to become $0.1 \mathrm{M}$ is . . . . . . . . . . sec. (nearest integer)
$(A)$ $\begin{matrix}
O\,\,\,\,\,\,\,\,\,\, \\
||\,\,\,\,\,\,\,\,\,\,\,\, \\
R-C-NHBr \\
\end{matrix}$ $(B)$ $R-NH-Br$
$(C)$ $R-N=C=O$ $(D)$ $\begin{matrix}
\,\,\,\,O\,\,\,\,\,\,\,\,\,\, \\
\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\, \\
R-C-NB{{r}_{2}} \\
\end{matrix}$
Reason : Hydrated $BaO_2$ is not available.