MCQ
Which is incorrect
- ✓$Ni (CO)_4 -$ Tetrahedral, Paramagnetic
- B$[Ni(CN)_4]^{-2} -$ Square planar, diamagnetic
- C$Ni(CO)_4 -$ Tetrahedral, diamagnetic
- D$[NiCl_4]^{-2} -$ Tetrahedral, Paramagnetic
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$(a)$ Number of $S-S$ bonds in $H_2S_nO_6$ are $(n +1)$
$(b)$ When $F_2$ reacts with $H_2O$ it forms $HF,$ $O_2$ & $O_3.$
$(c)$ $XeF_6$ on hydrolysis shows disproportionation reaction
$(d)$ $Al$ metal on reacting with dilute $NaOH$ gives a white precipitate of $Al (OH)_3$ as a final product
$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$
rate law is $R = K\, [NO_2]' [O_3]'$.
Which of these possible reaction mechanisms is consistent with the rate law?
Mechanism $I :$
$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)
Mechanism $II :$
$O_3(g) \rightleftharpoons O_2(g) + [O]$ (fast)
$NO_2(g) + [O] \to NO_3$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5$ (fast)
$(i)$ Ionic
$(ii)$ Covalent
$(iii)$ Coordinate