- A$Na{H_2}P{O_3}$
- B$Na{H_2}P{O_2}$
- C$N{a_3}H{P_2}{O_6}$
- ✓$N{a_4}{P_2}{O_7}$
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$\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - C{H_3}(excess) + B{r_2}\xrightarrow{{hv}}}
\end{array}$ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,C{H_3}} \\
| \\
{C{H_3} - C - C{H_3}} \\
| \\
{\,\,Br}
\end{array}}\limits_{(A)} $ + $\mathop {\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,} \\
{\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - C{H_2} - Br}
\end{array}}\limits_{(B)} $
the percentage yields of the products $(A)$ and $(B)$ are expected to be
Given : $\log 3=0.48$
$A.$ Reaction completes in $1000\,s$.
$B.$ The reaction has a half-life of $500\, s$.
$C.$ The time required for $10\, \%$ completion is 25 times the time required for $90 \,\%$ completion.
$D.$ The degree of dissociation is equal to $\left(1-e^{-k t}\right)$.
$E.$ The rate and the rate constant have the same unit.
Reason : Zinc is a powerful reducing agent than copper.
$I.\,H_2S_2O_6\,\,\,\,\,\,\,\,II.\,H_2SO_3\,\,\,\,\,\,\,\,III.\,H_2SO_5$