Chemistry in Everyday Life — Chemistry STD 12 Science — Question

$\frac{{ - d\left[ {{N_2}{O_5}} \right]}}{{dt}} = k\left[ {{N_2}{O_5}} \right]$ , 

$\frac{{d\left[ {N{O_2}} \right]}}{{dt}} = k'\left[ {{N_2}{O_5}} \right]$,

$\frac{{d\left[ {{O_2}} \right]}}{{dt}} = k''\left[ {{N_2}{O_5}} \right]$

The relationship between $k$ and $k'$ and between $k$ and $k^{"}$ are

$\begin{matrix}
   O\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   ||\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}-C-Cl-N{{H}_{3}}  \\
\end{matrix}$ $\to $ Inter mediate $\to $ product