Question
Which of the following biphenyls is optically active?
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$(I)\,K_3 [Fe(CN_6)]$ $(II)\, [Ni(CO)_4]^0$ $(III)\, [Cr(NH_3)_6]^{3+}$ $(IV)\, [Mn(CN)_6]^{4-}$
Choose the correct code
| List $-I$ | List $-II$ |
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$A.$ Melting point $[\mathrm{K}]$ |
$I.$ $\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}>\mathrm{Al}>\mathrm{B}$ |
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$B.$ Ionic Radius $\left[\mathrm{M}^{+3} / \mathrm{pm}\right]$ |
$II.$ $\mathrm{B}>\mathrm{Tl}>\mathrm{Al} \approx \mathrm{Ga}>\mathrm{In}$ |
| $C.$ $\Delta_{\mathrm{i}} \mathrm{H}_1 $ $ [\mathrm{~kJ} \mathrm{~mol}^{-1}]$ | $III.$ $\mathrm{Tl}>\mathrm{In}>\mathrm{Al}>\mathrm{Ga}>\mathrm{B}$ |
| $D.$ Atomic Radius $[pm]$ | $IV.$ $\mathrm{B}>\mathrm{Al}>\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}$ |
$(A)$ $\left[\mathrm{Pt}(\mathrm{en}) \mathrm{Cl}_2\right]$ $(B)$ $\left[\mathrm{Pt}(\mathrm{en})_2\right] \mathrm{Cl}_2$
$(C)$ $\left[\mathrm{Pt}(\text { en })_2 \mathrm{Cl}_2\right] \mathrm{Cl}_2$ $(D)$ $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]$
$(A)$ The total number of stereoisomers possible for ${X}$ is $6$
$(B)$ The total number of diastereomers possible for ${X}$ is $3$
$(C)$ If the stereochemistry about the double bond in ${X}$ is trans, the number of enantiomers possible for ${X}$ is $4$
$(D)$ If the stereochemistry about the double bond in ${X}$ is cis, the number of enantiomers possible for ${X}$ is $2$