MCQ
Which of the following has diamagnetic character
  • A
    ${[NiC{l_4}]^{2 - }}$
  • B
    ${[Co{F_6}]^{3 - }}$
  • C
    ${[Fe{({H_2}O)_6}]^{2 + }}$
  • ${[Ni{(CN)_4}]^{2 - }}$

Answer

Correct option: D.
${[Ni{(CN)_4}]^{2 - }}$
d
(d) $Ni$  in presence of $C{N^ - }$

$Ni^{+2}$ in presence $C{N^ - } = [Ar]$

As ${[Ni{(CN)_4}]^{2 - }}$ has no unpaired electron. It is diamagnetic.

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