p -Block elements - ll — Chemistry STD 12 Science — Question

Reason : Oxygen forms $p\pi \,-\, p\pi $ multiple bond due to small size and small bond length but $p\pi \,-\,p\pi $ bonding is not possible in sulphur.

In the above first order reaction the initial concentration of $\mathrm{N}_{2} \mathrm{O}_{5}$ is $2.40 \times 10^{-2}\, \mathrm{~mol} \,\mathrm{~L}^{-1}$ at $318 \,K.$ The concentration of $\mathrm{N}_{2} \mathrm{O}_{5}$ after $1\, hour$ was $1.60 \times 10^{-2}\, \mathrm{~mol} \,\mathrm{~L}^{-1}$, The rate constant of the reaction at $318\, \mathrm{~K}$ is $.....\,\times 10^{-3} \mathrm{~min}^{-1}$. (Nearest integer)

[Given: $\log 3=0.477, \log 5=0.699$ ]

Assertion $A$ : $Image-I$ can be easily reduced using $Zn - Hg / HCl$ to $Image-II$

Reason $R : Zn - Hg / HCl$ is used to reduce carbonyl group to $- CH _2-$ group.

In the light of the above statements, choose the correct answer from the options given below: