MCQ
Which of the following is not electrophile
  • $C{H_3} - C{H_2} - \mathop O\limits^ \oplus  {H_2}$
  • B
    $C{H_3} - Br$
  • C
    $Br_2$
  • D
    $CH_3-CH=CH_2$

Answer

Correct option: A.
$C{H_3} - C{H_2} - \mathop O\limits^ \oplus  {H_2}$
a
The order of reactivity of the benzene rings toward the electrophilic substitution when it is substituted with a activating group increases as the substituents on the ring are groups that donate electrons. $- CH _3$ is an activating group which makes benzene more reactive towards electrophile while- $COOH$ is a deactivating group which makes it less reactive.

The order reactivity towards the eletrophilic substitution of the compounds Toluene($I$)$\,>\,$ benzene($II$) $\,>\,$ Benzoicacid($III$)

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$\begin{array}{*{20}{c}}
  {C{H_3} - CH = CH - CH - CH - C{H_3}} \\ 
  {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} |{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} |{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,{\mkern 1mu} {\mkern 1mu} \,\,\,{\mkern 1mu} {\mkern 1mu} OH\,\,} 
\end{array}\,$

For a non $-$ volatile solute :