- A${N_2}$
- B${C_2}$
- ✓$N_2^ + $
- D$O_2^{2 - }$
${C_2}:KK\sigma{(2s)^2}\sigma*{(2s)^2}\pi {(2{p_x})^2}\pi {(2{p_y})^2}$ (diamagnetic)
$N_2^ + :KK\sigma{(2s)^2}\sigma*{(2s)^2}\pi {(2{p_x})^2}\pi {(2{p_y})^2}\sigma {(2{p_z})^2}$ (paramagnetic)
$O_2^{2 - }:KK\sigma{(2s)^2}\sigma*{(2s)^2}\sigma^* {(2{p_z})^2}\pi {(2{p_x})^2}\pi {(2{p_y})^2}$
$\pi *{(2{p_x})^2}\pi *{(2{p_y})^2}$ (diamagnetic)
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Which conformer of above compound is most stable across $C_2 - C_3$ ?
$C{H_3}COOH\xrightarrow{{LiAl{H_4}}}A\mathop {\xrightarrow{{{H^ + }}}}\limits_{443\,K} B\xrightarrow{{B{r_2}}}C\mathop {\xrightarrow{{alc.}}}\limits_{KOH} D$
( $U$ : आंतरिक ऊर्जा (internal energy), $S$ : एंट्रॉपी (entropy), $p$ : दाब (pressure), $V$ : आयतन (volume), $R$ : गैस नियतांक (gas constant)
(दिया गयाः स्थिर आयतन पर गैस की मोलर ऊष्माधारिता (molar heat capacity at constant volume), $C_{V, m }$ का मान $\frac{5}{2} R$ है)