- APure metal is used at anode and impure metal at cathode.
- ✓Pure metal is used at cathode and impure metal at anode.
- CBoth can be possible $A$ and $B.$
- DNone of these.
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$Mn^{2+} +2e- \rightarrow Mn;\, E^o = -1.18\,V$
$2(Mn^{3+} +e^- \rightarrow Mn^{2+} )\,;\,E^o=+1.51\,V$
The $E^o$ for $3Mn^{2+} \rightarrow Mn+ 2Mn^{3+}$ will be :
$\underset{(A)}{\mathop{\begin{matrix}
O \\
|| \\
C{{H}_{3}}-C-C{{H}_{3}}, \\
\end{matrix}}}\,\,\,\,\,\underset{(B)}{\mathop{\begin{matrix}
\,\,\,\,\,\,O \\
\,\,\,\,\,\,|| \\
C{{H}_{3}}-C-H, \\
\end{matrix}}}\,\,\,\,\,\underset{(C)}{\mathop{\begin{matrix}
O\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
||\,\,\,\,\,\,\,\,\,\,\, \,\, \\
C{{H}_{3}}-C-C{{H}_{2}}-Cl, \\
\end{matrix}}}\,$ $\,\,\underset{(D)}{\mathop{\begin{matrix}
O \\
|| \\
H-C-H, \\
\end{matrix}}}\,\,\,\,\underset{(E)}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
Cl-C{{H}_{2}}-C-H \\
\end{matrix}}}\,$
$Z$ is :
$(A)$ The hypochlorite ion is the strongest conjugate base.
$(B)$ The molecular shape of only chlorate ion is influenced by the lone pair of electrons of $Cl$.
$(C)$ The hypochlorite and chlorate ions disproportionate to give rise to identical set of ions.
$(D)$ The hypochlorite ion oxidizes the sulfite ion.