$\begin{array}{*{20}{c}}{CHO}\\|\\{HCOH}\\|\\{HOCH}\\|\\{HCOH}\\|\\{C{H_2}OH}\\I\end{array}$ $\begin{array}{*{20}{c}}{CHO}\\|\\{HCOH}\\|\\{HCOH}\\|\\{HOCH}\\|\\{C{H_2}OH}\\{II}\end{array}$ $\begin{array}{*{20}{c}}{CHO}\\|\\{HCOH}\\|\\{HCOH}\\|\\{HCOH}\\|\\{C{H_2}OH}\\{III}\end{array}$
$(i)$ Glucose $+ ROH \quad \stackrel{\text { dry } HCl }{\longrightarrow}$ Acetal
$\xrightarrow[{{{\left( {C{H_3}CO} \right)}_2}O}]{{x\,eq.of}}$ acetyl derivative
$(ii)$ Glucose $\xrightarrow{{Ni/{H_2}}}A\xrightarrow[{{{\left( {C{H_3}CO} \right)}_2}O}]{{y\,\,eq.\,of}}$ acetyl derivative.
$(iii)$ Glucose $\xrightarrow[{{{\left( {C{H_3}CO} \right)}_2}O}]{{z\,ed.\,of}}$ acetyl derivative.
$' x ^{\prime},{ }^{\prime} y ^{\prime}$ and ${ }^{\prime} z^{\prime}$ in these reactions are respectively.

Penta acetate of glucose $\xrightarrow[{\operatorname{Re} agent}]{{Tollen's}}$ $+\,ve$ test $(A)$
Penta acetate of glucose $\xrightarrow{{Benedicts}}$ $+\,ve$ test $(B)$
Penta acetate of glucose $\xrightarrow[{\operatorname{Re} agent}]{{Schiffs}}$ $-\,ve$ test $(C)$
Penta acetate of glucose $\xrightarrow{{NaHS{O_3}}}$ $-\,ve$ test $(D)$