MCQ
Which of the following represents correctly the changes in thermodynamic properties during the formation of $1\, mol$ of an ideal binary solution
  • A

  • B


  • D

Answer

Correct option: C.

c
When $1\, mole$ of an ideal binary solution is prepared, the enthalpy of mixing is $Jmol ^{-1}$

As the mole fraction increases, the free energy change of mixing first decreases, reaches a minimum value and then increases.

With increase in the mole fraction, the value of the term $T \Delta S _{\text {mix }}$ first increases, reaches a maximum value and then decreases.

Hence, option $C$ correctly represents the changes in thermodynamic properties during the formation of $1\, mole$ of an ideal binary solution.

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