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The d & f Block Elements — Chemistry STD 12 Science — Question

Gujarat BoardEnglish MediumSTD 12 ScienceChemistryThe d & f Block Elements1 Mark
MCQ
Which of the following species do not exist?
  • A
    $\mathrm{PbF}_4$
  • B
    $\mathrm{PbCl}_4$
  • C
    $\mathrm{PbO}_2$
  • ✓
    $\mathrm{PbI}_4$
✓

Answer

Correct option: D.
$\mathrm{PbI}_4$
$\mathrm{PbF}_4$ exists but $\mathrm{Pbl}_4$ does not exist as $\mathrm {I_2}$ reduces $\text{Pb(II)}$ to $Pb$ and oxidizes $I$ to $\mathrm {I_2}$​. Since, $\mathrm {I_2}$ is not strong reducing agent to reduce Pb(II) to $Pb.$

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$(I)$ $\begin{array}{*{20}{c}}
  {C{H_2} - C{H_2} - C{H_2} - C{H_2}OH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
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$(II)$ $\begin{array}{*{20}{c}}
  {C{H_3} - C{H_2} - CH - C{H_2}OH} \\ 
  {|\,} \\ 
  {N{O_2}} 
\end{array}$

$(III)$ $\begin{array}{*{20}{c}}
  {C{H_3} - CH - C{H_2} - C{H_2}OH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {N{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}$

$(IV)$ $CH_3-CH_2-CH_2-CH_2OH$

Select answer from codes given below :

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$\underset{(A)}{\mathop{\begin{matrix}
   \,\,\,\,\,Ph\,\,\,\,C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,|\,\,  \\
   Ph-C-C-C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,|\,\,\,  \\
   \,OH\,\,\,OH  \\
\end{matrix}}}\,+\underset{(B)}{\mathop{\begin{matrix}
   \,\,\,\,Ph\,\,\,Et  \\
   \,\,|\,\,\,\,\,\,\,\,\,|  \\
   Ph-C-C-Et  \\
   \,\,|\,\,\,\,\,\,\,\,\,|  \\
   \,\,\,\,\,OH\,\,OH  \\
\end{matrix}}}\,\xrightarrow{{{H}_{2}}S{{O}_{4}}}$

 

$(p)$ $\begin{matrix}
   Ph\,\,\,\,\,O\,  \\
   |\,\,\,\,\,\,\,\,||\,\,  \\
   Ph-C-C-C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\,  \\
\end{matrix}$                                $(q)$ $\begin{matrix}
   \,Ph\,\,\,\,\,O\,  \\
   \,\,|\,\,\,\,\,\,\,\,||  \\
   Ph-C-C-Et  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   Et\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}$

$(r)$ $\begin{matrix}
   \,Ph\,\,\,\,\,O\,  \\
   |\,\,\,\,\,\,\,\,\,\,||\,  \\
   Ph-C-C-C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   Et\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}$                             $(s)$ $\begin{matrix}
   \,\,\,Ph\,\,\,\,\,O\,  \\
   \,\,|\,\,\,\,\,\,\,\,||  \\
   Ph-C-C-Et  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,  \\
\end{matrix}$

When $(A)$ and $(B)$ reacts with $H_2SO_4$ products obtained are

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