MCQ
Which of the following statements is incorrect
  • A
    For elementary reactions the order of reaction and molecularity are identical
  • B
    For rate determining step the order and molecularity are identical
  • C
    Catalyst does not affect $\Delta H$ (Heat of reaction) of a chemical reaction
  • The activation energy of reaction decreases with increase in temperature

Answer

Correct option: D.
The activation energy of reaction decreases with increase in temperature
d

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$I.$ $CH_3 -CH = CH_2$ $\xrightarrow[{{\text{(CC}}{{\text{l}}_4}{\text{ )}}}]{{{\text{C}}{{\text{l}}_2}}}$ $\begin{array}{*{20}{c}}
{Cl\,\,}\\
{\,\,|\,\,\,\,\,}\\
{C{H_3} - CH - C{H_2}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Cl}
\end{array}$

$II.$ $\begin{array}{*{20}{c}}
O\\
{||}\\
{C{H_3} - C - C{H_3}}
\end{array}$ $\xrightarrow[{{}^\Theta OH}]{{{\text{HCN}}}}$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,OH}\\
|\\
{C{H_3} - C - C{H_3}}\\
|\\
{\,\,\,\,\,CN}
\end{array}$

$III.$ $CH_3-CH_2-CH_3$ $\xrightarrow[{hv}]{{C{l_2}}}$ $\begin{array}{*{20}{c}}
{Cl\,\,}\\
{|\,\,\,\,}\\
{C{H_3} - CH - C{H_3}}
\end{array}$