MCQ
Which one of the following is not a buffer solution
- A$0.8\,M\,{H_2}S + 0.8\,M\,KHS$
- B$2\,M\,{C_6}{H_5}N{H_2} + 2M\,{C_6}{H_5}\mathop N\limits^ + {H_3}\,Br$
- C$3\,M\,{H_2}C{O_3} + 3\,M\,KHC{O_3}$
- ✓$0.05\,M\,KCl{O_4} + 0.05\,M\,HCl{O_4}$
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(Given : $\Delta_{\mathrm{r}} \mathrm{H}_{298 \mathrm{~K}}^{\circ}=-54.07 \mathrm{~kJ} \mathrm{~mol}^{-1}, \Delta_{\mathrm{I}} \mathrm{S}_{298 \mathrm{~K}}^{\circ}=10 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$ and $\mathrm{R}=8.314 \mathrm{JK}^{-1} \mathrm{~mol}^{-1} ; 2.303 \times 8.314 \times 298=5705$ )

Which one of the following options represents identical molecules?