- ACarbonates
- ✓Sulphides
- COxides
- DPhosphates
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$(i) \,\,\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - C - CH - C{H_3}} \\
{\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,OH}
\end{array}\,\xrightarrow{{{H^ + }/heat}}\,\,\mathop A\limits_{[Major\,product]} \, + \,\mathop B\limits_{[Minor\,product]} $
$(ii)\,\, A\xrightarrow[{in\,\,absence\,\,\,of\,peroxide}]{{HBr,\,dark}}\,\,\mathop C\limits_{[Major\,product]} \, + \,\mathop D\limits_{[Minor\,product]} $
the major products $(A)$ and $(C)$ are respectively
$2 \mathrm{~K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}+8 \mathrm{H}_{2} \mathrm{SO}_{4}+3 \mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O} \rightarrow 2 \mathrm{Cr}_{2}\left(\mathrm{SO}_{4}\right)_{3}+$
$3 \mathrm{C}_{2} \mathrm{H}_{4} \mathrm{O}_{2}+2 \mathrm{~K}_{2} \mathrm{SO}_{4}+11 \mathrm{H}_{2} \mathrm{O}$
If the rate of appearance of $\mathrm{Cr}_{2}\left(\mathrm{SO}_{4}\right)_{3}$ is $2.67 \,\mathrm{~mol}$ $\min ^{-1}$ at a particular time, the rate of disappearance of $\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}$ at the same time is ...... $\mathrm{mol}\, \mathrm{min}^{-1}$ (Nearest integer)
(Given atomic number: $\mathrm{C}: 6, \mathrm{Na}: 11, \mathrm{O}: 8$, $\mathrm{Fe}: 26, \mathrm{Cr}: 24 \mathrm{~J}$