MCQ
Which would exhibit ionisation isomerism
  • A
    $\left[ {Cr{{\left( {N{H_3}} \right)}_6}} \right]C{l_3}$
  • $\left[ {Co{{\left( {N{H_3}} \right)}_5}Br} \right]S{O_4}$
  • C
    $\left[ {Cr{{(en)}_2}C{l_2}} \right]$
  • D
    $\left[ {Cr{{(en)}_3}C{l_3}} \right]$

Answer

Correct option: B.
$\left[ {Co{{\left( {N{H_3}} \right)}_5}Br} \right]S{O_4}$
b
(b) The compound which has same composition but give different ions in solution, show ionization. So $[Co{(N{H_3})_5}Br]$$SO_4^{}$ is ionization isomer.

$[Co{(N{H_3})_5}Br]S{O_4}$$ \rightleftharpoons $ ${[Co{(N{H_3})_5}Br]^{2 + }} + SO_4^{2 - }$

$[Co{(N{H_3})_5}S{O_4}]Br$$ \rightleftharpoons $ ${[Co(N{H_3})S{O_4}]^ + } + B{r^ - }$.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Amongst $FeCl _{3} \cdot 3 H _{2} O , \quad K _{3}\left[ Fe ( CN )_{6}\right]$ and $\left[ Co \left( NH _{3}\right)_{6}\right] Cl _{3}$, the spin-only magnetic moment value of the inner-orbital complex that absorbs light at shortest wavelength is $B.M.\,......$ [nearest integer]
Match $List-I$ with $List-II$

$List-I$ $List-II$
$A.$ Benzenesulphonyl chloride $I.$ Test for primary amines
$B.$ Hoffmann bromamide reaction $II.$ Anti Saytzeff
$C.$ Carbylamine reaction $III.$ Hinsberg reagent
$D.$ Hoffmann orientation $IV.$ Known reaction of Isocyanates.

Choose the correct answer from the options given below.

The colour of $CoC{l_3}.5N{H_3}.{H_2}O$ is
Which of the following reactant in reactions can reduced by $SO_2$

$(I)\,\, O_3 \to $ product

$(II)\,\,C{r_2}O_7^{ - 2}\xrightarrow{{{H^ + }}}$ product

$(III)\,\,MnO_4^\Theta \xrightarrow{{{H^ + }}}$ product

$(IV)\,\, H_2S \to $ product

The mismatched combinations are

$A.$ Chlorophyll - Co

$B.$ Water hardness - EDTA

$C.$ Photography $-\left[ Ag ( CN )_2\right]^{-}$

$D.$ Wilkinson catalyst - $\left[\left(P h_3 P\right)_3 R h C l\right]$

$E.$ Chelating ligand - D - Penicillamine

Choose the correct answer from the options given below:

Which of the following will react with water
In which of the following reaction cyanide will be obtained as a major product
....... $\sec$ is the $3^{rd}$ half life of the second order decomposition of a compound, given that its first half life is $20\, s$.
For a first order reaction, rate constant is 0.6932hr−1, then half - life for the reaction is:
The CFSE for octahedral [CoCl6]4- is 18,000cm-1. The CFSE for tetrahedral [CoCl4]2- will be: