Question
Write main differences between the properties of white phosphorus and red phosphorus.
| White phosphorus | Red phosphorus |
|
It is a soft and waxy solid.
It possesses a garlic smell |
It is a hard and crystalline solid, without any smell.
|
|
It is poisonous.
|
It is non-poisonous.
|
|
It is insoluble in water but soluble in carbon
disulphide. |
It is insoluble in both water and carbon disulphide.
|
|
It undergoes spontaneous
combustion in air. |
It is relatively less reactive.
|
|
In both solid and vapour
states, it exists as a $P_4$ molecule. ![]() |
It exists as a chain of tetrahedral $P_4$ units.
![]() |
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| $Cr^{2+}/Cr$ | $- 0.9 V$ | $Cr^3/Cr^{2+}$ | $- 0.4 V$ |
| $Mn^{2+}/Mn$ | $- 1.2 V$ | $Mn^{3+}/Mn^{2+}$ | $+ 1.5 V$ |
| $Fe^{2+}/Fe$ | $- 0.4 V$ | $Fe^{3+}/Fe^{2+}$ | $+ 0.8 V$ |

| t (sec) | P(mm of Hg) |
| $0$ | $35.0$ |
| $360$ | $54.0$ |
| $720$ | $63.0$ |