Question
Write structures of different isomers corresponding to the molecular formula, C3H9N. Write IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.
Propan - 1 - amine(pri)
$ \ \ \ \ \ \ \ \ \ \ \ \text{NH}_2\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ |\\\text{CH}_3-\text{CH}-\text{CH}_3$
N-methylethanamine (Sec)
primary amine, (a) Propan - 1 - amine, and (b) Propan - 2 - amine will liberate nitrogen gas on treatment with nitrous acid.
$\text{CH}_3\text{CH}_2\text{CH}_2\text{NH}_2+\text{HNO}_2\rightarrow\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}+\text{N}_2+\text{HCl}\\\text{Propan-1-amine} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Propan-1-ol}$
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The standard electrode potential (Eo) for Deniell cell is +1.1V. Calculated the ʌGo for the reaction
Zn (s) + Cu2+ (aq)
$\rightarrow$ Zn2 (aq) + Cu (s)(1 F = 96500 C mol-1).