Question
Write the significance/applications of dipole moment.

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Match the ions given in Column I with their nature given in Column II.
 
Column I
 
Column II
(i)
(a)
Stable due to resonance.
(ii)
$\text{F}_3-\text{C}^\oplus$
(b)
Destabilised due to inductive effect.
(iii)
$\ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3\\\ \ \ \ \ \ \ \ \ \ \ \ \ |\\\text{CH}_3-\text{C}^\ominus\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ |\\\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$
(c)
Stabilised by hyperconjugation.
(iv)
$\ \ \ \ \ \ \ \ \ \ \ \ \ _\oplus\\\text{CH}_3-\text{CH}-\text{CH}_3$
(d)
A secondary carbocation.
Derive the Rydberg formula.
The first ionization constant of H2S is 9.1 × 10–8. Calculate the concentration of HS ion in its 0.1M solution. How will this concentration be affected if the solution is 0.1M in HCl also ? If the second dissociation constant of H2S is 1.2 × 10–13, calculate the concentration of S2– under both conditions.
One of the reaction that takes place in producing steel from iron ore is the
reduction of iron(II) oxide by carbon monoxide to give iron metal and CO2.
$\text{FeO (S) + CO (g)}\rightleftharpoons\text{Fe (S) + CO}_2\text{ (g)};\text{ K}_{\text{p}}=0.265\text{atm at}1050\text{K}$
What are the equilibrium partial pressures of CO and CO2 at 1050 K if the initial partial pressures are: pCO= 1.4atm and = 0.80atm?
An organic compound contains 69% carbon and 4.8% hydrogen, the remainder being oxygen. Calculate the masses of carbon dioxide and water produced when 0.20g of this substance is subjected to complete combustion.
1. What is the general molecular formula of saturated monohydric alcohols?
2. Write structural formulae for compounds named as-
a. 1-Bromoheptane
b. 5-Bromoheptanoic acid
An aqueous solution contains an unknown concentration of Ba2+. When 50mL of 1M solution of Na2SO4 is added, BaSO4 first begin to precipitate. The final volume is 500mL. The solubility product of BaSO4 is 1.0 × 10-10. What is original concentration of Ba2+?
  1. $\text{MnO}_4^{2-}$ undergoes disproportionation reaction in acidic medium but does not, give reason.
  2. Give one example each of the following redox reaction:
  1. Combination reaction.
  2. Decomposition reaction.
  3. Metal displacement reaction.
Compare the acidic properties of alkane, alkene and alkyne and write reaction to represent the acidic nature of 1-alkyne.