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16 questions · timed · auto-graded

Question 11 Mark
Explain why are alcohols comparatively more soluble in water than the corresponding hydrocarbons?
Answer
Alcohols are relatively more soluble in water than the corresponding hydrocarbons because alcohol molecules can form hydrogen bonds with water. Hydrocarbons do not form hydrogen bonds with water.
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Question 21 Mark
Predict the reagent for carrying out the following conversions :
(i) Phenol to benzoquinone
(ii) Anisole to p-bromoanisole
(iii) Phenol to 2, 4, 6-tribromophenol
Answer
(i) $K _2 Cr _2 O _7+ H _2 SO _4 / Na _2 CrO _7+ H _2 SO _4$
(ii) $Br _2$ in $CH _3 COOH$
(iii) $Br _2( aq )$  Bromine water
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Question 31 Mark
Give one chemical reaction to distinguish ethanol and diethyl ether.
Answer
Hydrogen gas is evolved when sodium reacts with ethanol while diethyl ether does not react with sodium.
$ C_{2}H_{5}OH + Na \rightarrow C_{2}H_{5}ONa + H_{2} $
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Question 41 Mark
Phenols are more acidic than alcohols. Explain.
Answer
Phenols are more acidic then alcohols due to the formation of stable phenoxide ion and it also have resonance stabilisation but alcohols do not.
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Question 61 Mark
Phenol is more acidic than alcohol. Why?
Answer
Phenol is more acidic than alcohols due to the stablisation of phenoxide ion trhough resonance. Phenoxide ion is more stable than alkoxide ion.
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Question 71 Mark
Why does diethyl ether not react with sodium?
Answer
Diethyl ether does not react with sodium because hydrogen atom is not attached to the electronegative oxygen atom. In the absence of available hydrogen or other ionic species the sodium will not react with diethyl ether.
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Question 81 Mark
Explain why alcohols having same molecular weight are more soluble than the corresponding hydrocarbons.
Answer
Alcohols are more soluble in water because they make hydrogen bond with water as compared to same molecular weight hydrocarbon.
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Question 91 Mark
Explain reason that aqueous solution of alcohol is bad conductor of electricity.
Answer
Alcohol has intermolecular bonding present in thus its aqueous solution have no ion present in it.
Due to absence of ions its aqueous solution is bad conductor of electricity.
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Question 111 Mark
Why are Grignard reagents soluble in ether but not in benzene?
Answer
Grignard reagent forms complex with ether but not with benzene because ether has lone pair of electrons while benzene does not have lone pair of electrons to form coordinate complex.
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Question 121 Mark
Why are ethers insoluble in water?
Answer
Due to larger size of alkyl groups, the oxygen atom in ethers does not form intermolecular H-bonding with water.
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Question 131 Mark
Phenol has smaller dipole moment than methanol.###Why are dipole moments of phenol smaller than dipole moments of alcohols ?
Answer
Due to electron withdrawing effect of benzene ring the C-O bond in phenol is less polar but in case of methanol due to electron donating effect of $ CH_{3} $ group C-O bond is more polar.
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Question 141 Mark
Ortho-nitrophenol is more acidic than ortho-methoxyphenol. Give reason.
Answer
o-methoxyphenoxide ion left after the loss of a proton is destabilized by resonance. But o-nitphenoxide ion is stabilized by resonance thereby making o-nitrophenol stronger acid.
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Question 161 Mark
Anhydrous $ CaCl_{2} $ is not recommended as a drying agent for alcohols and amines. Why?
Answer
Alcohols and amines combine with anhydrous $ CaCl_{2} $ to form complexes. For example, with $ C_{2}H_{5}OH $, it gives a complex of molecular formula, $ CaCl_{2}, 3C_{2}H_{5}OH $.
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1 Marks Question - Chemistry STD 12 Science Questions - Vidyadip