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Question 511 Mark
Why is Lewis concept more useful than Bronsted Lowry concept?
Answer
Lewis concept includes some of compounds like $\mathrm{BF}_3, \mathrm{BCl}_3, \mathrm{AlCl}_3$ as acids which Bronsted Lowry concept does not.
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Question 521 Mark
Is it possible to get precipitate of Is it possible to get precipitate of $\mathrm{Fe}(\mathrm{OH})_3$ at $\mathrm{pH}=2$ ? Give reason.? Give reason.
Answer
No, because $\mathrm{Fe}(\mathrm{OH})_3$ will dissolve in strongly acidic medium.
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Question 531 Mark
Why pH of our blood remains constant at 7.4 through we quite often eat spicy food?
Answer
Blood contains basic buffer which keep its pH constant.
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Question 541 Mark
Write the expression for the equilibrium constant ($\text{K}_{\text{c}}$) for the reaction:
$\text{CH}_3\text{COOC}_2\text{H}_5(\text{aq})+\text{H}_2\text{O(l)}\\\rightleftharpoons\text{CH}_3\text{COOH}
(\text{aq})+\text{C}_2\text{H}_5\text{OH}(\text{aq})$
Answer
$\text{K}_{\text{c}}=\frac{[\text{CH}_3\text{COOH}][\text{C}_2\text{H}_5\text{OH}]}{[\text{CH}_3\text{COOC}_2\text{H}_2\text{H}_5][\text{H}_2\text{O}]}$
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Question 551 Mark
Which of the following is strongest Lewis acid? $\text{CCl}_4,\text{AlCl}_3,\text{NCl}_3,\text{OCl}_2$
Answer
$\text{AlCl}_3$ is strongest Lewis acid because its octet is not complete.
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Question 561 Mark
Write the equilibrium constant expression for following reaction:
$2\text{NOCl}(\text{g})\rightleftharpoons2\text{NO(g)}+\text{Cl}_2(\text{g})$
Answer
$\text{K}=\frac{[\text{NO}^2][\text{Cl}_2]}{[\text{NOCl}^2]}$
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Question 571 Mark
$\text{SO}_3^{2-}$ is Bronsted base or acid and why?
Answer
$\text{SO}_3^{2-}$ is Bronsted base because it can accept $\text{H}^+$.
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Question 581 Mark
What is the conjugate base of $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$?
Answer
$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{OH}\right]^{2+}$ is conjugate base of $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$.
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Question 591 Mark
Fizz is observed when soda water bottle is opened. Why?
Answer
Pressure is decreased, solubility of $\text{CO}_2$ in water decreases, $\text{CO}_2$ escapes from cold drink bottle.
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Question 601 Mark
Which of the following is strongest conjugate base? $\text{CH}_3^-,\text{NH}^-_2,\text{OH}^-,\text{F}^-$
Answer
$\text{CH}_4^-$ is strongest conjugate base because $\text{CH}_4$ is weakest acid, i.e., cannot donate $\text{H}^+$ easily.
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Question 611 Mark
Write expression of $\text{K}_{\text{c}}$ for reaction:
$\text{N}_2(\text{g})+3\text{H}_2(\text{g})\rightleftharpoons2\text{NH}_3(\text{g})$
Give units of K.
Answer
$\text{K}=\frac{[\text{NH}_3]^2}{[\text{N}_2][\text{H}_2]^3}$
$=\frac{(\text{mol L}^{-1})^2}{(\text{mol}^{-1})(\text{mol L}^{-1})^3}=\text{L}^2\text{mol}^{-2}$
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Question 621 Mark
How does common ion affect the solubility of electrolyte?
Answer
Solubility of electroyte decreases due to common ion effect.
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Question 631 Mark
Write the conjugate acid for the Bronsted base $\text{C}_6\text{H}_5\text{OH},\text{H}_2\text{O}$
Answer
$\ \ \ \ \ \ \ \ \oplus{}\ \ \ \ \ \ \ \ \ \ \oplus{}\\\text{C}_6\text{H}_5\text{OH}_2,\text{H}_3\text{O}$
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Question 641 Mark
Classify the following as Lewis acid or Lewis base: $\text{NH}_4^+\text{ and }\text{NH}_3$
Answer
$\text{NH}^+_4$ Lewis acid, whereas $\text{NH}_3$ is Lewis base.
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Question 651 Mark
What happens to ionic product of water if some acid is added to it?
Answer
Ionic product will remain unchanged.
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Question 661 Mark
If $Q_c<K_c$, in which direction reaction will proceed?
Answer
If $Q_c<K_c$, the reaction will proceed in the direction of products.
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