Question types

1. Solution and colligative properties question types

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Sample Questions

1. Solution and colligative properties questions

One sample from each question group in this chapter. Select any group above to see the full set with answer keys.

The plot of osmotic pressure (П) vs concentration $\left(\mathrm{mol} \mathrm{L}^{-1}\right)$ for a solution gives a straight line with slope $25.73 \mathrm{~L} \mathrm{bar} \mathrm{mol}^{-1}$. The temperature at which the osmotic pressure measurement is done is

(Use $\mathrm{R}=0.083 \mathrm{~L}$ bar mol $\mathrm{m}^{-1} \mathrm{~K}^{-1}$ )

  • A
     $310^{\circ} \mathrm{C}$
  • B
    $25.73^{\circ} \mathrm{C}$
  • C
     $12.05^{\circ} \mathrm{C}$
  •  $37^{\circ} \mathrm{C}$

Answer: D.

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The Henry's law constant $\left(\mathrm{K}_H\right)$ values of three gases $(A, B, C)$ in water are $145,2 \times 10^{-5}$ and $35$ kbar, respectively. The solubility of these gases in water follow the order:
  • A
     $B>C>A$
  • B
     $A>C>B$
  • C
    $A > B > C$
  • D
    $B > A > C$
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The following solutions were prepared by dissolving $10\, \mathrm{~g}$ of glucose $\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)$ in $250 \,\mathrm{ml}$ of water $\left(\mathrm{P}_{1}\right)$, $10\, \mathrm{~g}$ of urea $\left(\mathrm{CH}_{4} \mathrm{~N}_{2} \mathrm{O}\right)$ in $250\, \mathrm{ml}$ of water $\left(\mathrm{P}_{2}\right)$ and $10\, \mathrm{~g}$ of sucrose $\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)$ in $250\, \mathrm{ml}$ of water $\left(\mathrm{P}_{3}\right)$. The right option for the decreasing order of osmotic pressure of these solutions is :
  • $\mathrm{P}_{2}>\mathrm{P}_{1}>\mathrm{P}_{3}$
  • B
    $\mathrm{P}_{1}>\mathrm{P}_{2}>\mathrm{P}_{3}$
  • C
    $\mathrm{P}_{2}>\mathrm{P}_{3}>\mathrm{P}_{1}$
  • D
    $\mathrm{P}_{3}>\mathrm{P}_{1}>\mathrm{P}_{2}$

Answer: A.

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The correct option for the value of vapour pressure of a solution at $45^{\circ} \mathrm{C}$ with benzene to octane in molar ratio $3: 2$ is  ...... $\mathrm{mm}$ of $\mathrm{Hg}$

[At $45^{\circ} \mathrm{C}$ vapour pressure of benzene is $280\, \mathrm{~mm} \,\mathrm{Hg}$ and that of octane is $420\, \mathrm{~mm} \,\mathrm{Hg}$. Assume Ideal gas]

  • A
    $160$
  • B
    $168$
  • C
    $336$
  • D
    $350$
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