'+6' on S = {0, 1, 2, 3, 4, 5} defined by, $\text{a}+_6\text{b}=\begin{cases}\text{a}+\text{b},&\text{if a}+\text{b}<6\\\text{a}+\text{b}-6,&\text{if a}+\text{b}\geq6\end{cases}$
$\therefore\ \text{a}+_6\text{b}\in\text{S}$ for $\text{a, b}\in\text{S}$
$\therefore$ +6 defined a binary operation on S.