Given, the ratio of the volume of two spheres = 64 : 27
$\frac{\text{V}_1}{\text{V}_2}=\frac{64}{27}\Rightarrow\frac{\frac{4}{3}\pi\text{r}^3_1}{\frac{4}{3}\pi\text{r}^3_2{}}=\frac{64}{27}$
$\Rightarrow\ \ \ \Big(\frac{\text{r}_1}{\text{r}_2}\Big)^3=\Big(\frac{4}{3}\Big)^3\ \Big[\because\text{volume of sphere}=\frac{4}{3}\pi\text{r}^3\Big]$
$\Rightarrow\frac{\text{r}_1}{\text{r}_2}=\frac{4}{3}$
Let the surface areas of the two spheres be S1 and S2.
$\therefore\ \ \ \frac{\text{S}_1}{\text{S}_2}=\frac{4\pi\text{r}^2_1}{4\pi\text{r}^2_2}=\Big(\frac{\text{r}_1}{\text{r}_2}\Big)^2\ \ \ \ \Rightarrow\text{S}_1:\text{S}_2=\Big(\frac{4}{3}\Big)^2=\frac{16}{9}$
$\Rightarrow\ \ \ \text{S}_1:\text{S}_2=16:9$
Hence, the ratio of the their surface areas is 16 : 9.