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MCQ 11 Mark
Lowering of vapour pressure of solution
  • A
    is a property of solute
  • B
    is a property of solute as well as solvent
  • C
    is a property of solvent
  • is a colligative property
Answer
Correct option: D.
is a colligative property
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MCQ 21 Mark
Colligative property depends only on ………………. in a solution.
  • Number of solute particles
  • B
    Number of solvent particles
  • C
    Nature of solute particles
  • D
    Nature of solvent particles
Answer
Correct option: A.
Number of solute particles
Number of solute particles
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MCQ 31 Mark
When partial pressure of solvent in solution of nonvolatile solute is plotted against its mole fraction, nature of graph is
  • a straight line passing through origin
  • B
    a straight line parallel to mole fraction of solvent
  • C
    a straight line parallel to vapour pressure of solvent
  • D
    a straight line intersecting vapour pressure axis
Answer
Correct option: A.
a straight line passing through origin
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MCQ 41 Mark
Partial pressure of solvent in solution of non-volatile solute is given by equation,
  • A
    P = x2P0
  • B
    P0 = xP
  • P = x1P0
  • D
    P0 = x1P
Answer
Correct option: C.
P = x1P0
P = x1P0
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MCQ 51 Mark
According to the Raoult’s law, the relative lowering of vapour pressure is equal to the
  • A
    mole fraction of solvent
  • mole fraction of solute
  • C
    independent of mole fraction of solute
  • D
    molality of solution
Answer
Correct option: B.
mole fraction of solute
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MCQ 61 Mark
van't Haff factor for $K _4\left[ FeC ( N )_6\right]$ dissociated $10 \%$ is
  • A
    1.1
  • 1.4
  • C
    0.86
  • D
    1.6
Answer
Correct option: B.
1.4
1.4
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MCQ 71 Mark
The value of van’t Hoff factor will be minimum for
  • A
    0.05 M AlCl3
  • B
    0.2 M NaNO3
  • 5.0 M glucose
  • D
    0.1 M H2SO4
Answer
Correct option: C.
5.0 M glucose
5.0 M glucose
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MCQ 81 Mark
The van’t Hoff factor for an aqueous solution of an electrolyte is
  • A
    less than 1
  • B
    zero
  • greater than 1
  • D
    equal to 1
Answer
Correct option: C.
greater than 1
greater than 1
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MCQ 91 Mark
Abnormal molar mass is produced by
  • A
    association of solute
  • B
    dissociation of solute
  • both association and dissociation of solute
  • D
    separation by semipermeable membrane
Answer
Correct option: C.
both association and dissociation of solute
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MCQ 101 Mark
5 % solution of glucose is isotonic with a solution of urea (M = 60). Hence the weight of urea present in the solution is
  • 1.67 g
  • B
    6.0 g
  • C
    18.6 g
  • D
    1.2 g
Answer
Correct option: A.
1.67 g
1.67 g
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MCQ 111 Mark
A temperature at which 0.1 M KCl solution will have osmotic pressure 10 atm will be
  • A
    408 °C
  • B
    263 °C
  • C
    310 °C
  • 337 °C
Answer
Correct option: D.
337 °C
337 °C
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MCQ 121 Mark
Vapour pressure of solution of a nonvolatile solute is always
  • A
    equal to the vapour pressure of pure solvent
  • B
    higher than vapour pressure of pure solvent
  • lower than vapour pressure of pure solvent
  • D
    constant
Answer
Correct option: C.
lower than vapour pressure of pure solvent
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MCQ 131 Mark
The osmotic pressure of 0.2 M KCl solution at 310 K is
  • 10.17 atm
  • B
    5.084 atm
  • C
    8.36 atm
  • D
    12.2 atm
Answer
Correct option: A.
10.17 atm
10.17 atm
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MCQ 141 Mark
If $a, b, c$ and $d$ are the van't Hoff factors for $Na _2 SO _4$, glucose and $K _4\left[ Fe ( CN )_6\right]$ then
  • A
    $a > b > c$
  • B
    $a < b < c$
  • $b < a < c$
  • D
    $c < a < b$
Answer
Correct option: C.
$b < a < c$
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MCQ 151 Mark
The osmotic pressure of 0.1 M HCl solution at 27 °C will be
  • A
    2.46 atm
  • B
    0.164 atm
  • 4.92 atm
  • D
    0.0082 atm
Answer
Correct option: C.
4.92 atm
4.92 atm
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MCQ 161 Mark
0.2 M urea solution can be isotonic with
  • 0.1 M KBr solution
  • B
    0.1 M glucose solution
  • C
    0.15 m NaCl solution
  • D
    0.2 M KBr solution
Answer
Correct option: A.
0.1 M KBr solution
0.1 M KBr solution
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MCQ 171 Mark
$\Delta T _{ b } / m$ for NaBr solution will have value $\left( K _{ b }=0.52 K kg mol ^{-1}\right)$
  • A
    $0.52 K mol -1$
  • B
    $0.104 K kg mol-1$
  • C
    $1.24 kg mol ^{-1}$
  • $1.04 K kg mol -1$
Answer
Correct option: D.
$1.04 K kg mol -1$
$1.04 K kg mol -1$
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MCQ 181 Mark
The molar mass of acetic acid obtained by measuring depression in freezing point is $115.8 gmol ^{-1}$. Hence the degree of association is
  • A
    0.482
  • 0.964
  • C
    0.883
  • D
    1.12
Answer
Correct option: B.
0.964
0.964
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MCQ 191 Mark
If equimolar solutions of urea, NaCl , sucrose and $BaCl _2$ have boiling points $A , B , C$ and D , then
  • $A = C < B < D$
  • B
    A = D < B < C
  • C
    A > B > C < D
  • D
    A < B < C < D
Answer
Correct option: A.
$A = C < B < D$
A = C < B < D
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MCQ 201 Mark
Which of the following 0.1 M aqueous solutions will exert highest osmotic pressure ?
  • $Al _2\left( SO _4\right)_3$
  • B
    $Na _2 SO _4$
  • C
    $MgCl _2$
  • D
    KCl
Answer
Correct option: A.
$Al _2\left( SO _4\right)_3$
$Al _2\left( SO _4\right)_3$
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MCQ 211 Mark
The vapour pressure of water is 15.5 mm at 20 °C. The lowering of vapour pressure of 0.02 m K Br solution will be
  • 0.0112 mm Hg
  • B
    0.0056 mm Hg
  • C
    0.056 mm Hg
  • D
    0.31 mm Hg
Answer
Correct option: A.
0.0112 mm Hg
0.0112 mm Hg
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MCQ 221 Mark
If Kb for water is $0.52 Km ^{-1}$, the boiling point of 0.2 m solution of a nonvolatile solute will be
  • A
    371.96 K
  • 373.104 K
  • C
    373.52 K
  • D
    374.0 K
Answer
Correct option: B.
373.104 K
373.104 K
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MCQ 231 Mark
$5 \times 10-3 kg$ of urea is dissolved in $2 \times 10^{-2} kg$ of water. The percentage by weight of urea is
  • A
    $15 \%$
  • $20\%$
  • C
    $25\%$
  • D
    $30\%$
Answer
Correct option: B.
$20\%$
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MCQ 241 Mark
Isotonic solutions are the solutions having the same
  • A
    surface tension
  • B
    vapour pressure
  • osmotic pressure
  • D
    viscosity
Answer
Correct option: C.
osmotic pressure
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MCQ 251 Mark
The solution A is twice hypertonic to the solution B at a given temperature. If the solution A contains $8.6 \times 10^{22}$ molecules, then the number of molecules present in B are,
  • A
    $8.6 \times 10^{22}$
  • B
    $1.73 \times 10^{23}$
  • C
    $3.24 \times 10^{22}$
  • $4.3 \times 10^{22}$​​​​​​​
Answer
Correct option: D.
$4.3 \times 10^{22}$​​​​​​​
$4.3 \times 10^{22}$
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MCQ 261 Mark
$0.1 M$ solution of A has osmotic pressure $xNm ^{-2}$ at $300 K$ . If $200 ml$ of A and $100 ml$ of $0.2 M$ solution of nonreactive solute $B$ are mixed then the osmotic pressure will be
  • A
    3x
  • B
    0.05 x
  • 1.33 x
  • D
    0.75 x
Answer
Correct option: C.
1.33 x
1.33 x
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MCQ 271 Mark
The osmotic pressure of 5% glucose solution at 300 K is
  • $6.93 \times 10^5 Nm ^{-2}$
  • B
    $6.93 \times 10^2 Nm ^{-2}$
  • C
    $6.83 Pa$
  • D
    $6.00 \times 10^3 Pa$
Answer
Correct option: A.
$6.93 \times 10^5 Nm ^{-2}$
$6.93 \times 10^5 Nm ^{-2}$
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MCQ 281 Mark
A mango kept in a salt solution shrinks. Hence the liquid content in mango with respect to the salt solution is
  • A
    isotonic
  • B
    hypertonic
  • hypotonic
  • D
    equimolar
Answer
Correct option: C.
hypotonic
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MCQ 291 Mark
As temperature increases
  • A
    Osmotic pressure and vapour pressure decrease
  • Vapour pressure and osmotic pressure increase
  • C
    Vapour pressure increases but osmotic pressure decreases
  • D
    Osmotic pressure increases but vapour pressure decreases
Answer
Correct option: B.
Vapour pressure and osmotic pressure increase
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MCQ 301 Mark
In osmosis
  • A
    solvent molecules pass from high concentration of solute to low concentration
  • solvent molecules pass from a solution of low concentration of solute to a solution of high concentration of solute
  • C
    solute molecules pass from low concentration to high concentration
  • D
    solute molecules pass from high concentration to low concentration
Answer
Correct option: B.
solvent molecules pass from a solution of low concentration of solute to a solution of high concentration of solute
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MCQ 311 Mark
At a freezing point,
  • A
    Vapour pressure of a solution = Vapour pressure of a solid
  • Vapour pressure of a liquid = Vapour pressure of a solid
  • C
    Vapour pressure of a liquid > Vapour pressure of a solid
  • D
    Vapour pressure of a solid > Vapour pressure of a liquid
Answer
Correct option: B.
Vapour pressure of a liquid = Vapour pressure of a solid
Vapour pressure of a liquid = Vapour pressure of a solid
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MCQ 321 Mark
If the freezing point of 0.1 m solution is 272.814 K, then the freezing point of 0.2 m solution will be
  • A
    545.628 K
  • B
    265.64 K
  • 272.628 K
  • D
    0.482 K
Answer
Correct option: C.
272.628 K
272.628 K
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MCQ 331 Mark
Which of the following solutions shows maximum depression in freezing point ?
  • A
    $0.5 M Li _2 SO _4$
  • B
    $1 M NaCl$
  • $0.5 M Al _2\left( SO _4\right)_3$
  • D
    $0.5 M BaCl _2$
Answer
Correct option: C.
$0.5 M Al _2\left( SO _4\right)_3$
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MCQ 341 Mark
10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant molarity of solution is
  • A
    0.25 M
  • B
    0.5 M
  • 1.0 M
  • D
    0.1 M
Answer
Correct option: C.
1.0 M
1.0 M
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MCQ 351 Mark
Which of the following aqueous solutions will have minimum elevation in boiling point ?
  • A
    $0.1 M KCl$
  • $0.05 M NaCl$
  • C
    $1 M AlPO _4$
  • D
    $0.1 M MgSO _4$
Answer
Correct option: B.
$0.05 M NaCl$
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MCQ 361 Mark
The determination of molar mass from elevation in boiling point is called
  • A
    cryoscopy
  • B
    osmometry
  • ebullioscopy
  • D
    spectroscopy
Answer
Correct option: C.
ebullioscopy
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MCQ 371 Mark
Molal elevation constant is elevation in boiling point produced by
  • A
    1 g of solute in 100 g of solvent
  • B
    100 g of solute in 1000 g of solvent
  • C
    1 mole of solute in one litre of solvent
  • 1 mole of solute in one kg of solvent
Answer
Correct option: D.
1 mole of solute in one kg of solvent
1 mole of solute in one kg of solvent
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MCQ 381 Mark
A solution having the highest vapour pressure is
  • A
    $1 M Al _2\left( SO _4\right)_3$
  • $0.1 M NaNO _3$
  • C
    $1 M BaCl _2$
  • D
    $1 M Ca \left( NO _3\right)_2$
Answer
Correct option: B.
$0.1 M NaNO _3$
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MCQ 391 Mark
The addition of the nonvolatile solute into the pure solvent ……………..
  • A
    increases the vapour pressure of solvent
  • B
    decreases the boiling point of solvent
  • decreases the freezing point of solvent
  • D
    increases the freezing point of solvent
Answer
Correct option: C.
decreases the freezing point of solvent
decreases the freezing point of solvent
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MCQ 401 Mark
$14$. A solution having mole fraction of a solute equal to $0.05$ has vapour pressure $20 \times 10^3 Nm ^{-2}$. Hence the vapour pressure of a pure solvent is
  • $21.05 \times 10^3 Nm ^{-2}$
  • B
    $4 \times 10^5 Nm ^{-2}$
  • C
    $1 \times 10^3 Nm ^{-2}$
  • D
    $2 \times 10^4 Nm ^{-2}$
Answer
Correct option: A.
$21.05 \times 10^3 Nm ^{-2}$
$21.05 \times 10^3 Nm ^{-2}$
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MCQ 411 Mark
Relative vapour pressure lowering depends only on
  • Mole fraction of solute
  • B
    Nature of solvent
  • C
    Nature of solute
  • D
    Nature of solute and solvent
Answer
Correct option: A.
Mole fraction of solute
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MCQ 421 Mark
The vapour pressure of an aqueous solution of glucose at 100 °C is 710 mm Hg. Hence the molality of the solution is
  • A
    2.83 m
  • 3.65 m
  • C
    16.47 m
  • D
    12.5 m
Answer
Correct option: B.
3.65 m
3.65 m
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MCQ 431 Mark
The relative lowering of vapour pressure of a solution is proportional to the
  • A
    mole fraction of the solvent
  • mole fraction of the solute
  • C
    amount of the substance
  • D
    volume of the solvent
Answer
Correct option: B.
mole fraction of the solute
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MCQ 441 Mark
Raoult’s law is not applicable to
  • A
    solutions of volatile solutes
  • B
    solutions of electrolytes
  • C
    dilute solutions
  • concentrated solutions
Answer
Correct option: D.
concentrated solutions
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MCQ 451 Mark
A molal solution is one that contains one mole of solute in
  • A
    one litre of the solvent
  • 1000 g of the solvent
  • C
    one litre of the solution
  • D
    22.4 litre of solution
Answer
Correct option: B.
1000 g of the solvent
1000 g of the solvent
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MCQ 461 Mark
What is vapour pressure of a solution containing $1.8 \mathrm{~g}$ glucose in $16.2 \mathrm{~g}$ of water if vapour pressure of water is $32 \mathrm{~mm} \mathrm{Hg}$ ?
  • A
    $22 \cdot 2 \mathrm{~mm} \mathrm{Hg}$
  • B
    $24 \cdot 6 \mathrm{~mm} \mathrm{Hg}$
  • C
    $26 \cdot 6 \mathrm{~mm} \mathrm{Hg}$
  • $31 \cdot 7 \mathrm{~mm} \mathrm{Hg}$
Answer
Correct option: D.
$31 \cdot 7 \mathrm{~mm} \mathrm{Hg}$
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MCQ 471 Mark
Which of following salts solubility increases appreciably with increase in temperature?
  • A
    $\mathrm{NaCl}$
  • $\mathrm{KNO}_3$
  • C
    $\mathrm{NaBr}$
  • D
    $\mathrm{KCl}$
Answer
Correct option: B.
$\mathrm{KNO}_3$
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MCQ 481 Mark
Calculate freezing point of a 0.05 molal aqueous solution of a non electrolyte? $\left(\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right.$, freezing point of water $\left.=0^0 \mathrm{C}\right)$
  • $272 \cdot 9 \mathrm{~K}$
  • B
    $93 \mathrm{~K}$
  • C
    $186 \mathrm{~K}$
  • D
    $279 \mathrm{~K}$
Answer
Correct option: A.
$272 \cdot 9 \mathrm{~K}$
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MCQ 491 Mark
Calculate the molality of a solution having freezing point depression $3.6 \mathrm{~K}$ and freezing point depression constant $4.8 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$.
  • $0.75 \mathrm{~mol} \mathrm{~kg}^{-1}$
  • B
    $0.9 \mathrm{~mol} \mathrm{~kg}^{-1}$
  • C
    $0.5 \mathrm{~mol} \mathrm{~kg}^{-1}$
  • D
    $0.3 \mathrm{~mol} \mathrm{~kg}^{-1}$
Answer
Correct option: A.
$0.75 \mathrm{~mol} \mathrm{~kg}^{-1}$
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MCQ 501 Mark
Calculate the molar mass of solute when 1.5 gram non volatile solute dissolved in $100 \mathrm{~mL}$ solvent having density $0.8 \mathrm{~g} \mathrm{~mL}^{-1}$ lowers its freezing point by $0.75 \mathrm{~K}$.(Freezing point depression constant for solvent is $5 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ )
  • A
    $75 \mathrm{~g} \mathrm{~mol}^{-1}$
  • B
    $100 \mathrm{~g} \mathrm{~mol}^{-1}$
  • C
    $110 \mathrm{~g} \mathrm{~mol}^{-1}$
  • $125 \mathrm{~g} \mathrm{~mol}^{-1}$
Answer
Correct option: D.
$125 \mathrm{~g} \mathrm{~mol}^{-1}$
D
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MCQ - Chemistry STD 12 Questions - Vidyadip