Questions

Assertion (A) & Reason (B) MCQ

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4 questions · timed · auto-graded

Question 11 Mark
Assertion (A): Aldehydes and ketones show condensation reactions.
Reason (R): The hydrogen atoms attached to $\alpha$-carbon of aldehydes and ketones are reactive.
Answer
(a) Both A and R are true and R is the correct explanation of A.
Explanation: The release of hydrogen from $\alpha$-carbon of aldehydes or ketones results in the formation of carbanion which is resonance stabilised. It is called enolate. Enolate ion can act as as a nucleophile and can attack the carbonyl group of the other molecule, i.e. giving condensation reactions.
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Question 21 Mark
Assertion (A): Ammonolysis of alkyl halides is not a suitable method for the preparation of pure primary amines.
Reason (R): Ammonolysis of alkyl halides yields mainly secondary amines.
Answer
(c) Assertion (A) is true, but Reason (R) is false.
Explanation: The amine formed reacts further with more of alkyl halide to give 2º and 3º amines and finally quaternary salt
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Question 31 Mark
Assertion (A): Cellulose can be easily converted into fibres.
Reason (R): Cotton contains about 90% cellulose.
Answer
(b) Both A and R are true but R is not the correct explanation of A.
Explanation: Cellulose is a linear condensation polymer of β-glucose. Because of linear structure, cellulose can be easily converted into fibres.
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Question 41 Mark
Assertion $(A):$ Dehydration of glycerol with $\ce{KHSO_4}$ gives acrolein.
Reason $(R):$ Acrolein is an $\alpha , \beta-$unsaturated aldehyde.
Answer
Removal of two molecules of water gives a product which tautomerises to yield acrolein $-$an $\alpha, \beta-$unsaturated aldehyde.
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Assertion (A) & Reason (B) MCQ - Chemistry STD 12 Science Questions - Vidyadip