MCQ
Acetylene reacts with ammonical $AgN{O_3}$ forming
- ✓Silver acetylene
- BSilver acetate
- CMetal silver
- DSilver mirror
$C _2 H _2+2 AgNO _3+2 NH _4 OH \rightarrow C _2 Ag _2+2 NH _4 NO _3+2 H _2 O$
It is called Tollen's Test. The silver acetylide forms a white ppt. This test is used to determine the presence of a triple-bond in hydrocarbons.
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$(a)$ Polarising power of cation
$(b)$ Extent of distortion of anion
$(c)$ Polarisability of the anion
$(d)$ Polarising power of anion
$\begin{array}{|l|l|} \hline Product & Sulphide\,\,Solubility \\ \hline (I) & 1.74\,\,\times\,\,10^{-16} \\ \hline (II) & 1.2\,\,\times\,\,10^{-22} \\ \hline (III) & 8.2\,\,\times\,\,10^{-46} \\ \hline (IV) & 5.0\,\,\times\,\,10^{-34} \\ \hline \end{array}$
