- Ideal solution.
- Molarity (M).
The solution which obey Roult's law over entire range of concentration are known as ideal solution.
For ideal solution: Enthalpy of mixing of the pure components to form the solution, Δmix H = 0 and volume of mixing, Δmix V = 0
It is defined as the number of moles of solute present in 1000 mL of the solution. Molarity is represented by M.
$\text{Molarity (M)}=\frac{\text{Number of moles of solute}}{\text{ volume of solution in mL}}\times1000$
or
$\text{M} = \frac{\text{Weight of solute}}{\text{molar mass of solute}\times \text{Volume of solution in mL}}\times1000$
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| t (sec) | P(mm of Hg) |
| 0 | 35.0 |
| 360 | 54.0 |
| 720 | 63.0 |
Ag+(aq) + e- $\rightarrow$ Ag(s) Eo = +0.80 V
H+(aq) + e- $\rightarrow$ H2(g) Eo = 0.00 V
On the basis of their standard reduction electrode potential (Eo) values, which reaction is feasible at the cathode and why?