Question
Describe the $IUPAC$ rules of naming organic compounds.

Answer

IUPAC nomenclature system: International Union for Pure and Applied Chemistry (IUPAC) put forth a nomenclature system based on the structure of the compounds and it was accepted all over the world. There are three units in the IUPAC name of any carbon compound: parent, suffix and prefix. These are arranged in the name as follows: Prefix-parent-suffix:
An IUPAC name is given to a compound on the basis of the name of its parent alkane. The name of the compound is constructed by attaching appropriate suffix and prefix to the name of the parent-alkane. The steps in the IUPAC nomenclature of straight chain compounds are as follows: Step 1: Draw the structural formula of the straight chain compound and count the number of carbon atoms in it. The alkane with the same number of carbon atoms is the parent alkane of the concerned compound. Write the name of this alkane. In case the carbon chain of concerned compound contains a double bond, change the ending of the parent name from ‘ane’ to ‘ene’. If the carbon chain in the concerned compound contains a triple bond, change the ending of the parent name from ‘ane’ to ‘yne’.
Sr. No. Structural formula Straight chain Parent name
$1.$ $CH_3– CH_2– CH_3$ $C – C – C$ propane
$2.$ $CH_3– CH_2– OH$ $C – C$ ethane
$3.$ $CH_3– CH_2– COOH$ $C – C – C$ propane
$4.$ $CH_3– CH_2– CH_2– CHO$ $C – C – C – C$ butane
$5.$ $CH_3– CH = CH_2$ $C – C = C$ propene
$6.$ $CH_3– C ≡ CH$ $C – C ≡ C$ propyne

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