Question
Distinguish between a sigma and a pi bond.

Answer

Sr. No. Pi bond Sigma bond
1 Pi bond is formed by lateral overlapping of orbitals. Sigma bond is formed by end to end overlapping of orbitals.
2 It is comparatively weak bond. It is comparatively strong bond.
3 There is only one overlapping orbital is p-p. The overlapping orbitals are s-s, s-p, p-p.
4 Rotation around pi- bond is restricted. Rotation is possible around sigma bond.
5 Electron cloud is not symmetrical about the line joining 2 nuclei. Electron cloud is symmetrical about the line joining 2 nuclei.
6 It is having 2 electron clouds one above the plane of atomic nuclei and one below the plane of atomic nuclei. It is having 1 electron cloud and that is symmetrical about the inter-nuclear axis.

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