Question
Explain the nitration reaction of benzene.

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Naina was preparing a compound in the laboratory. She added compound $‘A \ ’$ to $(CaOH)_2$ solution. As a result of this, a compound $‘B \ ’$ was obtained which had a pungent smell. On adding Nessler’s reagent to the compound $‘B \ ’,$ a brown precipitate of compound $‘C \ ’$ was obtained.
Write the chemical reactions involved and identify $‘A \ ’, ‘B \ ’$ and $‘C \ ’.$
Nitrogen does not form $NCl5$ or $NF5$ but phosphorus can. Explain.
Complete the following reactions by mentioning the reagent/reaction conditions under which these reactions are carried out.Image
What are the limitations of valence bond theory?
Compound $“X”$ having the following structure is used as synthetic antioxidant to increase the shelf life of packed foods.
Image
$i.$ What is the molecular formula of compound $“X”$?
$ii.$ Identify the structural unit responsible for antioxidant activity of $“X”.$
$iii.$ Give one example of a compound with structure, similar to compound $“X”,$ which is commonly used as synthetic antioxidant.
$iv.$ Give the $\text{IUPAC}$ name of compound $“X”.$
Chalcopyrite $(CuFeS_2)$ is a common ore of copper. Since it has low concentration of copper, the ore is first concentrated through froth floatation process. The concentrated ore is then heated strongly with silicon dioxide $($silica$)$ and oxygen in a furnace. The product obtained, copper$(I)$ sulphide, is further converted to copper $(99.5\%$ pure$)$ with a final blast of air $(O_2)$ during which sulphur dioxide is released as a by$-$product.
$i.$ Write a balanced reaction for the extraction of copper from copper$(I)$ sulphide.
$ii.$ Which species undergoes an increase in the oxidation state?
$iii.$ Which species accepts electrons?
Complete the following table.Plant
Medicinal propertyActive ingredient
CinnamonAntimicrobial for cold————
————————Eugenol
Citrus fruitsAntioxidant————
Wintergreen————————
Indian gooseberry (amla)Antidiabetic, antimicrobial, antioxidantVitamin C, Gallic acid
How does dihydrogen react with various organic compounds to give useful, commercially important products?
Write a short note on magnetic orbital quantum number $(m_l).$
Draw orbital diagrams of
a. Fluorine molecule
b. Hydrogen fluoride molecule