Explain the relationship between basicity and structure of amines… - Vidyadip

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Explain the relationship between basicity and structure of amines.

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$t( sec )$	$P$ (mm of Hg )
0	35.0
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Answer the following questions:
Give reasons:

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The experimental data for decomposition of N₂O₅
$\left[2 N_2 O _5 \rightarrow 4 NO _2+ O _2\right]$
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t/s	$10^{-2} \times\left[ N _2 O _5\right] / mol L ^{-1}$
0	1.63
400	1.36
800	1.14
1200	0.93
1600	0.78
2000	0.64
2400	0.53
2800	0.43
3200	0.35

(i) Plot [N₂O₅] against t.
(ii) Find the half-life period for the reaction.
(iii) Draw a graph between log[N₂O₅] and t.
(iv) What is the rate law?
(v) Calculate the rate constant.
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