- ✓$(\Delta H - T\Delta S)$ must be negative
- B$(\Delta H + T\Delta S)$ must be negative
- C$\Delta H$ must be negative
- D$\Delta S$ must be negative
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|
List$-I$ (Chemical Reaction) |
List$-II$ (Reagent used) |
| $(a)$ $\mathrm{CH}_{3} \mathrm{COOCH}_{2} \mathrm{CH}_{3} \rightarrow \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}$ |
$(i)$ $\mathrm{CH}_{3} \mathrm{MgBr} / \mathrm{H}_{3} \mathrm{O}^{+}$ $(1 .$ equivalent $)$ |
| $(b)$ $\mathrm{CH}_{3} \mathrm{COOCH}_{3} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}$ | $(ii)$ $\mathrm{H}_{2} \mathrm{SO}_{4} / \mathrm{H}_{2} \mathrm{O}$ |
| $(c)$ $\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{N} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}$ | $(iii)$ $\mathrm{DIBAL}-\mathrm{H} / \mathrm{H}_{2} \mathrm{O}$ |
| $(d)$ $\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{N} \rightarrow \mathrm{CH}_{3}CO\mathrm{CH}_{3}$ | $(iv)$ $\mathrm{SnCl}_{2}, \mathrm{HCl} / \mathrm{H}_{2} \mathrm{O}$ |
Choose the most appropriate match :
$\begin{array}{*{20}{c}}
{{\,\,R_1}} \\
| \\
{R - C - X} \\
| \\
{{\,\,R_2}}
\end{array}\xrightarrow{{HOH}}\begin{array}{*{20}{c}}
{{\,\,R_1}\,\,\,\,} \\
{|\,\,\,\,} \\
{R - C - OH} \\
{|\,\,\,\,\,} \\
{{\,\,R_2}\,\,\,\,}
\end{array}$
Which substrate will give maximum racemisation ?
$Ni^{2+} | Ni = -0.25\, V$
$Cu^{2+} | Cu = 0.34\, V$
$Ag^+ | Ag = 0.80\, V$
$Zn^{2+} | Zn = -0.76\, V$
Which of the following reactions under standard condition will not take place in the specified direction